Brad Pitt and Angeline Jolie's Cutest Moments

A look back at Hollywood's biggest couple. View Gallery 40 Slides Though their romance is rumored to have started on the set of Mr. and Mrs. Smith back in 2004, Brad Pitt and Angelina Jolie didn't openly acknowledge their relationship until closer to 2005 and didn't tie the knot until just the summer of 2014.

  • Celebrity
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  • Brad Pitt and Angelina Jolie's Cutest Moments
  • A look back at Hollywood's biggest couple.

    By Published: Sep 20, 2016bookmarksSave ArticleUse Arrow Keys to Navigate

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    Though their romance is rumored to have started on the set of Mr. and Mrs. Smith back in 2004, Brad Pitt and Angelina Jolie didn't openly acknowledge their relationship until closer to 2005 and didn't tie the knot until just the summer of 2014. Two years later, they are reportedly splitting. Flip through to take a look back at your favorite A-list couple's cutest moments.

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    1

    2004

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    Filming Mr. and Mrs. Smith.

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    2

    June 2005

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    At the L.A. premiere of Mr. and Mrs. Smith.

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    3

    November 2006

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    In Vietnam.

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    4

    November 2006

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    With the family in Mumbai, India.

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    5

    January 2007

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    At the Golden Globe Awards.

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    6

    May 2007

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    At the Ocean's Thirteen premiere at Cannes Film Festival.

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    7

    May 2007

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    At a restaurant in Prague.

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    8

    June 2007

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    At the premiere of Ocean's Thirteen.

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    9

    June 2007

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    At the New York premiere of A Mighty Heart.

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    10

    September 2007

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    At the Toronto premiere of The Assassination of Jesse James by the Coward Robert Ford.

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    11

    November 2007

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    At the London premiere of Beowulf.

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    12

    December 2007

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    At the L.A. premiere of God Grew Tired of Us.

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    13

    January 2008

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    At the Critics' Choice Awards.

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    14

    January 2008

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    At the Screen Actors Guild Awards.

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    15

    May 2008

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    At the Kung Fu Panda premiere at Cannes Film Festival.

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    16

    July 2008

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    With newborn twins, Vivienne and Knox.

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    17

    October 2008

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    At the New York premiere of Changeling.

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    18

    January 2009

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    At the Berlin premiere of The Curious Case of Benjamin Button.

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    19

    January 2009

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    At the Japan premiere of The Curious Case of Benjamin Button.

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    20

    January 2009

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    At the Critics' Choice Awards.

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